The 54-year-old – whose outfit choices regularly go down a storm on Twitter – showed off her curves in the figure-hugging ensemble, which also consisted of a chunky black waist belt and a polka dot blouse with a plunging neckline.
Carol tied her blonde locks away from her face in a chic up 'do and she finished off the glamorous get-up with lashings of deep red lipstick.
The former Strictly Come Dancing star's army of fans, as per usual, immediately took to social media to gush over the presenter.
One person posted: "@carolkirkwood Blimey! How nice do u look wearing a tight leather skirt and belt! Hurry back on screen."
Carol Kirkwood swapped her usual dresses for a leather skirt on today's BBC Breakfast
Carol teamed the sexy skirt with a polka dot blouse
Wow looking good today Carol!
"With the wide belt/leather skirt, this looks like a Victoria Derbyshire show day today. Very chic," a second added.
A third wrote: "@carolkirkwood looking fab 2day Carol. Great outfit choice (sic)," as a fourth sang: "It is an itsy bitsy, teeny weeny black n white polka dot blouse thats being worn today, oh yeah."
A further viewer went on: "@carolkirkwood Tuned in at 7 and saw you wearing a tight leather skirt. I think you look so sexy in them. Can't wait for 7.15 now. #sexy x"
"@carolkirkwood wow looking good today xx," another social networker shared, alongside a wide-eyed emoji.
Carol Kirkwood in pictures
Thu, January 26, 2017
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BBC Weather presenter Carol Kirkwood in pictures. The TV presenter has won the TRIC Award for Best TV Weather Presenter five times.
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Carol Kirkwood looks sensational at the NTAs
Carol sent fans wild with her latest outfit choice
Despite the constant praise, Carol previously insisted that she still doesn't see herself as a "sex symbol".
Carol told Express.co.uk: "Sex symbol makes me laugh, I couldn’t be further from a sex symbol if I tried! I think I’m more just your girl-next-door rather than anything else. If anyone says that, bless them.
"I have to be honest, I don’t read all my tweets because I’m usually at work and posting on Twitter in between."
BBC Breakfast continues tomorrow from 6am.