Gomes and Cristiano Ronaldo are team-mates at international level with Portugal.
The Real Madrid star scored twice to fire the Spanish giants to a 2-1 win over Bayern Munich last night.
It means the former Manchester United forward became the first ever player to score a century of goals in the competition.
Cristiano Ronaldo fired Real Madrid past Bayern Munich last night Real Madrid transfer odds: Which Premier League aces could move? Thu, March 30, 2017
Click to reveal the best transfer odds for superstars moving to Real Madrid, courtesy of 888sport
Play slideshow GETTY 1 of 11
The latest transfer odds for Real Madrid's summer deals, courtesy of 888sport
Despite enduring a difficult season, Ronaldo continues to scale new heights.
And Spanish outlet Diario Gol claim the 32-year-old was congratulated on his achievement by Gomes.
In news that will be sure to annoy Lionel Messi, Gomes sent his compatriot a message praising him.
Reports have previously claimed that Messi is wary of his Barcelona team-mates' relationship with Ronaldo.
Cristiano Ronaldo and Andre Gomes are team-mates at international level
When he signed from Valencia for £23million in the summer, Messi viewed Gomes as one of Ronaldo's henchmen.
Get Quotes on Home Insurance
As a result, the Argentina international wants Gomes gone at the end of the season.
With Luis Enrique stepping down as manager in the summer, the midfielder could follow him out of the exit door.